Decarbonation reaction of magnesite in subducting slabs at the lower mantle     

N. Takafuji  K. Fujino  T. Nagai  Y. Seto  D. Hamane 《Physics and Chemistry of Minerals》2006,33(10):651-654

High-pressure and temperature experiments (28–62 GPa, and 1,490–2,000 K, corresponding to approximately 770–1,500 km depth in the mantle) have been conducted on a MgCO₃ + SiO₂ mixture using a laser-heated diamond anvil cell combined with analytical transmission electron microscope observation of the product phases to constrain the fate of carbonates carried on the subducting basalt into the lower mantle. At these conditions, the decarbonation reaction MgCO₃ (magnesite) + SiO₂ (stishovite) → MgSiO₃ (perovskite) + CO₂ (solid) has been recognized. This indicates that above reaction takes place as a candidate for decarbonation of the carbonated subducting mid ocean ridge basalts in the Earth’s lower mantle.  相似文献   

Evaluation of Simultaneous Analyte Leaching/Vapour Phase Introduction for Direct Osmium Isotope Ratio Measurements in Solid Samples by Double-Focusing Sector Field ICP-MS     

Ilia Rodushkin  Emma Engström  Douglas C. Baxter 《Geostandards and Geoanalytical Research》2007,31(1):27-38

The analytical performance of a method for Os isotope ratio measurement by double‐focusing, sector field ICP‐MS (ICP‐SFMS) was evaluated. The method is based on several optimised, concurrent processes: Os extraction from samples in hot concentrated nitric acid; separation of Os from the digest solution by the formation of volatile osmium tetroxide accelerated by continuous hydrogen peroxide addition; transport of analyte vapour by an oxygen flow into the ICP; and isotopic determination by ICP‐SFMS. Due to the very efficient utilisation of analyte (approaching 0.5‰), Os isotope ratio measurement could be performed at low pg levels. Combined with an ability to process sample sizes up to 2 g (up to 50 g if the organic matrix of biological or botanical samples is eliminated by ashing), materials with Os concentrations in the low, or even sub pg g^?1 range could be determined by this method. Given that two complete digestion/distillation systems were available for interchangeable use, throughputs of up to fifteen samples per 8 hour shift could be achieved. The method precision, evaluated as the long‐term reproducibility of ¹⁸⁷ Os/¹⁸⁸Os ratio measurements in a commercial Os reference sample containing 0.5 ng Os, was 0.16% relative standard deviation (RSD, 1s). The method has been applied to perform replicate ¹⁸⁷ Os/¹⁸⁸ Os ratio measurements on a suite of fifty reference materials of various origins and matrix compositions, with Os concentrations varying from < 0.1 pg g^?1 to > 100 ng g^?1, yielding an average precision of 3% RSD. Though none of the materials tested are certified for Os content or Os isotope composition, comparison of the obtained data with published Os isotope information for similar sample types revealed close agreement between the two. The method can also be used for the simultaneous, semi‐quantitative determination of Os concentrations.  相似文献   

内核地球自转动力学理论的研究进展(Ⅳ)——内核自转动力学方程          下载免费PDF全文

张捍卫  许厚泽  王爱生 《地球物理学进展》2006,21(4):1139-1144

本文是序列文章的第四篇，其内容包括：基于连续介质力学的基本理论，给出了固体外核（SIC）自转的动力学方程，考虑了地球的自引力、液核对内核边界的压力和二阶外部引潮力位对SIC自转的影响，并在O(mε)的量级上给出了其实用的表达式.本文的理论推导更加严密和细致，改正了文献〔1〕在推导过程中的某些错误（例如：（B39）、（B44）和（B59c）式）.本文的工作是对文献〔1〕有关理论的扩展和改进，对进一步研究内核地球自转的动力学理论是非常重要的.  相似文献   

固体潮观测数据预处理中的常用方法及计算机实现   总被引：1，自引：0，他引：1  

熊先保  黄晓华  牛其寿  徐智明  张远城 《地震地磁观测与研究》2006,27(4):98-101

从地震台站产出的原始地形变前兆数据出发,提出实际操作性较强的预处理方法,从已编制好的软件中给出处理实例,从而提高地震台站观测人员的科研能力,填补资料预处理方面的某些空白,对于地震台站人员集观测、科研于一体有着十分重要的意义。从95-01-02项目厦门地震台前兆数据预处理的实践表明:这些方法取得了明显的实效,直到今天仍然具有很大的使用价值。  相似文献   

海潮对数字垂直摆倾斜仪记录的影响浅析     

夏超德 《东北地震研究》2006,22(4):53-58

宁波地震台数字垂直摆倾斜仪记录的EW、NS向固体潮在同一数量级,与理论固体潮有较大的差异,且与浙江省其它地区地震台的记录迥然不同。该台倾斜资料与海水潮汐关系密切,用其分钟值绘出的矢量图日规律性较强。本文对此作了初步分析与探讨。  相似文献   

辽宁深井承压水位潮汐响应函数的初步研究   总被引：1，自引：0，他引：1  

唐九安  梁子斌  常千军  范五基 《东北地震研究》2006,22(1):5-10

介绍了辽宁省地震水动态监测网19口井固体潮汐响应函数的计算结果,基于M2波潮汐因子及其月离散相对误差,分析了各观测井潮汐响应函数对地壳应变的响应灵敏度、潮汐因子的动态稳定性和监测效能。结果表明:在所列19口观测井中,如果以M2波潮汐因子0.2m/10-9作为潮汐响应幅值的下限,则除甘沟子以外的18口井可用于潮汐响应函数的研究;如果以M2波潮汐因子的月离散相对误差20%作为选择观测井的上限,则除瓦房店楼房井、岫岩1井、周家井、丹东变电所井、牛四井、容2井和阜新市甘沟子等井以外的12口井可用于潮汐参数的动态特征研究。  相似文献   

Effect of some additives on synthesis of zeolite from coal fly ash   总被引：3，自引：0，他引：3  

Deyi Wu  Bohua Zhang  Li Yan  Hainan Kong  Xinze Wang 《International Journal of Mineral Processing》2006,80(2-4):266-272

Hydrothermal conversion of fly ash into zeolites was conducted and the effects of the addition of sodium halide and waste solutions produced after zeolitization of fly ash, as well as the adjustment of the Si/Al ratio prior to synthesis process on the formation and cation exchange capacity (CEC) of zeolite product were evaluated. Both the addition of NaCl and NaF ameliorated the crystallinity and CEC of synthesized zeolite, but NaF had a better improvement effect. Na⁺ was considered to enhance the crystallization of zeolite, while F⁻ favored the dissolution of fly ash. The type of zeolite formed depended on the Si/Al ratio of the starting material prior to the nucleation and crystallization of zeolite. The adjustment of the Si/Al ratio of fly ash by addition of Na₂SiO₄ and Al(OH)₃ changed the type and CEC of zeolite. Waste solutions contained large amount of Si and little Al due to the formation of a zeolite named NaP1 in zeolite terminology with the Joint Committee of Powder Diffraction Standard (JCPDS) code of 39-0219. The alkalinity decreased largely. As a result, the CEC value of zeolite products synthesized with waste solution as alkali source decreased. The supplementation of new alkali to adjust the alkalinity of waste solution could enhance the CEC of synthesized product. It was concluded that: (1) addition of sodium halide and adjustment of the Si/Al ratio prior to synthesis can improve the quality of zeolite; (2) waste solutions produced following the zeolitization of fly ash can be reused as an alkali source in the activation of fly ash; zero-emission of waste solution in the synthesis of zeolite from fly ash is possible.  相似文献   

CFC在中国高放废物处置库预选区地下水研究中的应用   总被引：1，自引：0，他引：1  

郭永海  王驹  王志明  刘淑芬  吕川河 《地球学报》2006,27(3):253-258

本文介绍了地下水测年的CFC方法及其原理,并将这种方法实际应用于我国高放废物处置库预选区——甘肃北山地区的水文地质研究,结果表明,研究区内沟谷洼地浅部地下水的CFC年龄在15~26a,基岩裂隙浅部地下水多为不含CFC的老水与含CFC的新水的混合水。在描述了确定混合比方法的基础上,根据样品CFC含量计算了研究区地下水的混合比。与氚相比,CFC是目前年轻地下水测年更好的工具,具有更多的优越性。  相似文献   

Wave propagation in a general anisotropic poroelastic medium: Biot’s theories and homogenisation theory     

M. D. Sharma 《Journal of Earth System Science》2007,116(4):357-367

Anisotropic wave propagation is studied in a fluid-saturated porous medium, using two different approaches. One is the dynamic approach of Biot’s theories. The other approach known as homogenisation theory, is based on the averaging process to derive macroscopic equations from the microscopic equations of motion. The medium considered is a general anisotropic poroelastic (APE) solid with a viscous fluid saturating its pores of anisotropic permeability. The wave propagation phenomenon in a saturated porous medium is explained through two relations. One defines modified Christoffel equations for the propagation of plane harmonic waves in the medium. The other defines a matrix to relate the relative displacement of fluid particles to the displacement of solid particles. The modified Christoffel equations are solved further to get a quartic equation whose roots represent complex velocities of the four attenuating quasi-waves in the medium. These complex velocities define the phase velocities of propagation and quality factors for attenuation of all the quasi-waves propagating along a given phase direction in three-dimensional space. The derivations in the mathematical models from different theories are compared in order to work out the equivalence between them. The variations of phase velocities and attenuation factors with the direction of phase propagation are computed, for a realistic numerical model. Differences between the velocities and attenuations of quasi-waves from the two approaches are exhibited numerically.  相似文献   

Experimental determination of saltating glass particle dispersion in a turbulent boundary layer     

H. T. Wang  X. H. Zhang  Z. B. Dong  M. Ayrault 《地球表面变化过程与地形》2006,31(14):1746-1762

A horizontal saltation layer of glass particles in air is investigated experimentally over a flat bed and also over a triangular ridge in a wind tunnel. Particle concentrations are measured by light scattering diffusion (LSD) and digital image processing, and velocities using particle image velocimetry (PIV). All the statistical moments of the particle concentration are determined such as mean concentration, root mean square concentration fluctuations, skewness and flatness coefficients. Over the flat bed, it is confirmed that the mean concentration decreases exponentially with height, the mean dispersion height being a significant length scale. It is shown that the concentration distribution follows quite well a lognormal distribution. Over the ridge, measurements were made at the top of the ridge and in the cavity region and are compared with measurements without the ridge. On the hill crest, particles are retarded, the saltation layer decreases in thickness and concentration is increased. Downwind of the ridge, particle flow behaves like a jet, in particular no particle return flow is observed. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献